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Dissolution of PuO2 in Hydrochloric Acid Medium—Effect of Reducing Agents

Mrs. Shakila Abdul Majeed, Thandangorai Ganapathi Srinivasan, Kanwal Nain Sabharwal

Nuclear Technology / Volume 88 / Number 3 / December 1989 / Pages 290-293

Technical Paper / Chemical Processing / dx.doi.org/10.13182/NT89-A34311

Studies on the dissolution of plutonium dioxide (PuO2) in hydrochloric acid medium, in the presence and absence of reducing agents such as hydrazine and iron, have been performed. The results indicate that hydrazine increases the dissolution of PuO2 even in low acidities, and low concentrations of Fe(II) are sufficient to bring about complete dissolution in a short period of time.