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Interaction of Curium Sesquioxide with Refractory Metal Matrices in Pressed and Sintered Cermet Compacts

J. A. Donovan, D. T. Rankin, J. E. Stuckey, P. K. Smith, W. R. McDonell

Nuclear Technology / Volume 13 / Number 3 / March 1972 / Pages 273-283

Technical Paper / Material / dx.doi.org/10.13182/NT72-A31082

No reaction was observed between B-type 244Cm2O3 and tungsten, molybdenum, or rhenium matrices in cermet compacts fabricated by cold pressing and sintering at temperatures up to 1850°C. Reaction was observed, however, between the oxide and tantalum matrices sintered as low as 1400°C. Cold pressing and sintering at the highest temperatures produced generally well-consolidated Cm2O3 refractory metal compacts of 85% or greater theoretical density. In compacts produced from well-mixed powders, the oxide was distributed uniformly in the metal matrix with little vaporization loss of Cm2Os.