Nuclear Science and Engineering / Volume 35 / Number 2 / February 1969 / Pages 159-164
Technical Paper / dx.doi.org/10.13182/NSE69-A21131
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Surface depletion was investigated in laboratory- and plant-scale distillation units with mixing by natural convection or by mechanical surface agitation. During the distillation of 210Po, Zn, Cd, Te, and Mg from bismuth at 650 to 750°C, surface depletion was significant for the more volatile components: 210Po, Zn, and Cd. The extent of surface depletion was decreased by relatively intense agitation of the entire liquid-metal surface. A model was developed for predicting the degree of surface depletion during the distillation of metals from bismuth as a function of temperature, still pot dimensions, and degree of agitation.