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Recovery of Hydrogen Isotopes and Impurity Mixture by Cryogenic Molecular Sieve Bed for GDC Gas Cleanup

Mikio Enoeda, Yoshinori Kawamura, Kenji Okuno, Ken-ichi Tanaka, Mitsuru Uetake, Masabumi Nishikawa

Fusion Science and Technology / Volume 28 / Number 3P1 / October 1995 / Pages 591-596

Tritium Processing / Proceedings of the Fifth Topical Meeting on Tritium Technology in Fission, Fusion, and Isotopic Applications Belgirate, Italy May 28-June 3, 1995 / dx.doi.org/10.13182/FST95-A30467

Experimental results showed that Q2 gas was adsorbed effectively by CMSB on an early stage of breakthrough even though CH4 exists in the inlet gas. Particularly, in the case of Q2 with low concentration of CH4, the break through curve of Q2 showed almost the same curve as in the case of pure Q2 adsorption. However, CH4 gas spilled over adsorbed Q2 in the course of CH4 break-through. This means that the CMSB will eventually lose the ability to adsorb Q2 in the final stage of adsorption. The critical time when the CMSB loses the adsorption ability depends on the inlet CH4 concentration. Analysis of the results showed that the adsorption of Q2 and CH4 mixture can be roughly described by assuming the multi-component adsorption equations for Q2 and CH4 using Langmuir's equations. It was certified that the analysis model described and predicted the experimental observations very well.